Stereostructures and conformations of four diterpene lactones from Gelonium multiflorum

Stereostructures and conformations of four diterpene lactones from Gelonium multiflorum

Talapatra B., Das G., Das A.K., Biswas K., Talapatra S.K.

Paper

Abstract

The stereostructures and molecular conformations of four more diterpene
lactones, gelomulides G-J, isolated as minor constituents from the leaves
of Gelonium multiflorum were established on the basis of their ^1H NMR,
^1^3C NMR and mass spectral evidence. Additionally, a 2D NMR spectral study
and the ORTEP diagram derived from the X-ray crystallographic analysis of
gelomulide I confirmed its proposed stereostructure and absolute
configuration.

Details

Keyword

Gelonium multiflorum, Euphorbiaceae, diterpene lactones, gelomulides G-J, molecular conformations, absolute configuration, X-ray crystallography

Publishing material
Phytochemistry. Vol.49 No.5, 1998年11月, p. 1353-1359