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Synthesis and Morphological Control of Organic Semiconducting Materials Using the Precursor Approach

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dc.contributor.author Yamada, Hiroko en
dc.contributor.author Hayashi, Hironobu en
dc.contributor.author Aratani, Naoki en
dc.date.accessioned 2020-10-28T05:36:11Z en
dc.date.available 2020-10-28T05:36:11Z en
dc.date.issued 2020-10-02 en
dc.identifier.uri http://hdl.handle.net/10061/14132 en
dc.description.abstract Pristine π-extended aromatic compounds are attractive as organic functional materials including organic semiconductors, but are difficult to synthesize in pure form because of their low solubility in common organic solvents. The precursor approach is a very useful method to synthesize pure π-extended aromatic compounds that cannot be prepared via traditional organic synthesis in flasks. In this approach, pure precursors are first prepared; these precursors are then converted quantitatively to the target molecules via a retro-Diels–Alder reaction or Strating–Zwanenburg photodecarbonylation reaction. This approach has also been used for the on-surface synthesis of the large acenes, heptacene and nonacene, under ultra-high vacuum in order to investigate their electronic properties, and is useful for the control of the packing structure of organic semiconductors in solution–processed films. The charge carrier mobilities of organic photovoltaics and organic field effect transistors have been improved using the precursor approach in combination with substituent effects. This account focuses on the synthesis and morphological control of aromatic compounds using the precursor approach in our group in the last decade. ja
dc.language.iso en en
dc.publisher Chemical Society of Japan en
dc.relation.isreplacedby https://www.journal.csj.jp/doi/10.1246/bcsj.20200130 en
dc.rights © 2020 The Chemical Society of Japan ja
dc.subject Precursor approach en
dc.subject Aromatic compounds en
dc.subject Organic semiconductors en
dc.title Synthesis and Morphological Control of Organic Semiconducting Materials Using the Precursor Approach en
dc.type.nii Journal Article en
dc.contributor.transcription ヤマダ, ヒロコ ja
dc.contributor.transcription ハヤシ, ヒロノブ ja
dc.contributor.transcription アラタニ, ナオキ ja
dc.contributor.alternative 山田, 容子 ja
dc.contributor.alternative 林, 宏暢 ja
dc.contributor.alternative 荒谷, 直樹 ja
dc.textversion none en
dc.identifier.eissn 1348-0634 en
dc.identifier.jtitle Bulletin of the Chemical Society of Japan en
dc.identifier.volume 93 en
dc.identifier.issue 10 en
dc.identifier.spage 1234 en
dc.identifier.epage 1267 en
dc.relation.doi 10.1246/bcsj.20200130 en
dc.identifier.NAIST-ID 73293565 en
dc.identifier.NAIST-ID 74650730 en
dc.identifier.NAIST-ID 73299042 en


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