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A Windmill-Shaped Molecule with Anthryl Blades to Form Smooth Hole-Transport Layers via a Photoprecursor Approach

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dc.contributor.author Maeda, Akihiro
dc.contributor.author Nakauchi, Aki
dc.contributor.author Shimizu, Yusuke
dc.contributor.author Terai, Kengo
dc.contributor.author Sugii, Shuhei
dc.contributor.author Hayashi, Hironobu
dc.contributor.author Aratani, Naoki
dc.contributor.author Suzuki, Mitsuharu
dc.contributor.author Yamada, Hiroko
dc.date.accessioned 2020-08-07T07:11:43Z
dc.date.available 2020-08-07T07:11:43Z
dc.date.issued 2020-05-18
dc.identifier.issn 1996-1944
dc.identifier.uri http://hdl.handle.net/10061/14017
dc.description.abstract Preparation of high-performance organic semiconductor devices requires precise control over the active-layer structure. To this end, we are working on the controlled deposition of small-molecule semiconductors through a photoprecursor approach wherein a soluble precursor compound is processed into a thin-film form and then converted to a target semiconductor by light irradiation. This approach can be applied to layer-by-layer solution deposition, enabling the preparation of p–i–n-type photovoltaic active layers by wet processing. However, molecular design principles are yet to be established toward obtaining desirable thin-film morphology via this unconventional method. Herein, we evaluate a new windmill-shaped molecule with anthryl blades, 1,3,5-tris(5-(anthracen-2-yl)thiophen-2-yl)benzene, which is designed to deposit via the photoprecursor approach for use as the p-sublayer in p–i–n-type organic photovoltaic devices (OPVs). The new compound is superior to the corresponding precedent p-sublayer materials in terms of forming smooth and homogeneous films, thereby leading to improved performance of p–i–n OPVs. Overall, this work demonstrates the effectiveness of the windmill-type architecture in preparing high-quality semiconducting thin films through the photoprecursor approach. ja_JP
dc.language.iso en ja_JP
dc.publisher MDPI ja_JP
dc.rights © 2020 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). ja_JP
dc.subject organic photovoltaics ja_JP
dc.subject morphology ja_JP
dc.subject layer-by-layer solution process ja_JP
dc.subject acenes ja_JP
dc.title A Windmill-Shaped Molecule with Anthryl Blades to Form Smooth Hole-Transport Layers via a Photoprecursor Approach ja_JP
dc.type.nii Journal Article ja_JP
dc.contributor.transcription ハヤシ, ヒロノブ
dc.contributor.transcription アラタニ, ナオキ
dc.contributor.transcription スズキ, ミツハル
dc.contributor.transcription ヤマダ, ヒロコ
dc.contributor.alternative 林, 宏暢
dc.contributor.alternative 荒谷, 直樹
dc.contributor.alternative 鈴木, 充朗
dc.contributor.alternative 山田, 容子
dc.textversion publisher ja_JP
dc.identifier.jtitle Materials / ja_JP
dc.identifier.volume 13 ja_JP
dc.identifier.issue 10 ja_JP
dc.relation.doi 10.3390/ma13102316 ja_JP
dc.identifier.NAIST-ID 74650730 ja_JP
dc.identifier.NAIST-ID 73299042 ja_JP
dc.identifier.NAIST-ID 73299935 ja_JP
dc.identifier.NAIST-ID 73293565 ja_JP


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