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Aggregation-induced scaffolding: photoscissable helical polysilane generates circularly polarized luminescent polyfluorene

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dc.contributor.author Abdul Rahim, Nor Azura en
dc.contributor.author Fujiki, Michiya en
dc.date.accessioned 2016-07-19T02:16:25Z en
dc.date.available 2016-07-19T02:16:25Z en
dc.date.issued 2016-06-10 en
dc.identifier.issn 1759-9954 en
dc.identifier.uri http://hdl.handle.net/10061/10665 en
dc.description.abstract An enantiopair of rigid rod-like helical polysilanes (PSi-S and PSi-R) as a photoscissible scaffold enabled the production of circularly polarised luminescence (CPL)- and circular dichroism (CD)-active di-n-octylpolyfluorene (PF8) aggregates associated with complete removal by PSi-selective photoscissoring at 313 nm. PF8 revealed a considerably high dissymmetry factor (gCPL) of (2–5) × 10−3 at 435 nm due to the chiral β-phase of PF8 after the 313 nm irradiation. ja
dc.language.iso en en
dc.publisher The Royal Society of Chemistry en
dc.rights © Royal Society of Chemistry 2016 ja
dc.rights 出版社許諾条件により、本文は2017年6月10日以降に公開。 ja
dc.title Aggregation-induced scaffolding: photoscissable helical polysilane generates circularly polarized luminescent polyfluorene en
dc.type.nii Journal Article en
dc.contributor.transcription フジキ, ミチヤ ja
dc.contributor.alternative 藤木, 道也 ja
dc.textversion author en
dc.identifier.abstracturl http://pubs.rsc.org/en/Content/ArticleLanding/2016/PY/C6PY00595K#!divAbstract en
dc.identifier.jtitle Polymer Chemistry en
dc.identifier.volume 7 en
dc.identifier.issue 28 en
dc.identifier.spage 4618 en
dc.identifier.epage 4629 en
dc.relation.doi 10.1039/C6PY00595K en
dc.identifier.NAIST-ID 73293300 en


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