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Equilibrium between inactive ready Ni-SIr and active Ni-SIa states of [NiFe] hydrogenase studied by utilizing Ni-SIr-to-Ni-SIa photoactivation†

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dc.contributor.author Tai, Hulin
dc.contributor.author Xu, Liyang
dc.contributor.author Nishikawa, Koji
dc.contributor.author Higuchi, Yoshiki
dc.contributor.author Hirota, Shun
dc.date.accessioned 2019-09-30T05:41:35Z
dc.date.available 2019-09-30T05:41:35Z
dc.date.issued 2017-09-19
dc.identifier.issn 1359-7345
dc.identifier.uri http://hdl.handle.net/10061/13383
dc.description.abstract Previously, the Ni-SIr state of [NiFe] hydrogenase was found to convert to the Ni-SIa state by light irradiation. Herein, large activation energies and a large kinetic isotope effect were obtained for the reconversion of the Ni-SIa state to the Ni-SIr state after the Ni-SIr-to-Ni-SIa photoactivation, suggesting that the Ni-SIa state reacts with H2O and leaves a bridging hydroxo ligand for the Ni-SIr state. ja_JP
dc.language.iso en ja_JP
dc.publisher Royal Society of Chemistry ja_JP
dc.rights ©The Royal Society of Chemistry 2017 ja_JP
dc.title Equilibrium between inactive ready Ni-SIr and active Ni-SIa states of [NiFe] hydrogenase studied by utilizing Ni-SIr-to-Ni-SIa photoactivation† ja_JP
dc.type.nii Journal Article ja_JP
dc.contributor.transcription ヒロタ, シュン
dc.contributor.alternative 廣田, 俊
dc.identifier.fulltexturl https://pubs.rsc.org/en/content/articlelanding/2017/cc/c7cc06061k#!divAbstract ja_JP
dc.textversion author ja_JP
dc.identifier.jtitle Chemical Communications ja_JP
dc.identifier.volume 53 ja_JP
dc.identifier.issue 75 ja_JP
dc.identifier.spage 10444 ja_JP
dc.identifier.epage 10447 ja_JP
dc.relation.doi info:doi/10.1039/C7CC06061K ja_JP
dc.identifier.NAIST-ID 73293425 ja_JP


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